Cui Zhou; Zhilin Tian; Liya Zheng; Sikai Wang; Tiefeng Du; Jiemin Wang; Bin Yang; Min Guo; Luchao Sun; Jingyang Wang

doi:10.1016/j.exm.2026.100021

PDF(18275 KB)

Extreme Materials ›› 2026, Vol. 2 ›› Issue (1) : 58-68. DOI: 10.1016/j.exm.2026.100021

Cui Zhou ^a^,^b ,
Zhilin Tian ^c ,
Liya Zheng ^c ,
Sikai Wang ^b^,^d ,
Tiefeng Du ^b ,
Jiemin Wang ^b ,
Bin Yang ^b ,
Min Guo ^e ,
Luchao Sun ^b^,^* ,
Jingyang Wang ^b^,^*

作者信息 +

Comparative study of water vapor corrosion resistance in directionally solidified RE₃Al₅O₁₂/Al₂O₃ eutectic ceramics at 1500°C: Effect of eutectic structure and rare earth elements

Cui Zhou ^a^,^b ,
Zhilin Tian ^c ,
Liya Zheng ^c ,
Sikai Wang ^b^,^d ,
Tiefeng Du ^b ,
Jiemin Wang ^b ,
Bin Yang ^b ,
Min Guo ^e ,
Luchao Sun ^b^,^* ,
Jingyang Wang ^b^,^*

Author information +

文章历史 +

Abstract

Al₂O₃-based directionally solidified eutectic (DSE) ceramics are recognized as promising candidates for high-temperature structural materials in advanced aeroengines. Nevertheless, their corrosion resistance at elevated temperatures continues to pose a critical challenge, limiting broader application in hot-section components. This study investigates corrosion behavior of RE₃Al₅O₁₂ (REAG)/Al₂O₃ (RE = rare earth) DSE ceramics in water vapor atmosphere (90 H₂O(g) + 10 vol% air(g)) at 1500°C for durations up to 200 h, with focus on the influence of eutectic structure and RE elements in garnet phases via examining three samples (high-entropy (Y_0.2Gd_0.2Ho_0.2Er_0.2Yb_0.2)₃Al₅O₁₂ DSEs fabricated at 10 and 300 mm/h and YAG/Al₂O₃ DSE grown at 10 mm/h). The results indicate that REAG/Al₂O₃ DSE ceramics exhibit excellent water vapor corrosion resistance at 1500°C for up to 200 h, with mass loss values ranging from −0.00757 to −0.00708 mg·cm⁻²·mg⁻¹. During corrosion, Al₂O₃ phase acts as corrosion-susceptible component compared to REAG phase, with corrosion depth showing a nearly linear relationship with the average Al₂O₃ lamellar width. In addition, garnet phases experience slight grain growth, reducing the contact area between water vapor and Al₂O₃ phase; Gd demonstrates the slowest diffusion rate when compared to other RE elements. Despite these changes, all samples maintain their preferred crystallographic orientations, confirming the structural stability of REAG/Al₂O₃ DSEs under water vapor atmosphere at 1500°C.

Key words

Water vapor corrosion / RE₃Al₅O₁₂/Al₂O₃ / Eutectic ceramic / Directional solidification

引用本文

EndNote

Ris (Procite)

Bibtex

导出引用

Cui Zhou, Zhilin Tian, Liya Zheng, 等. [J]. Extreme Materials. 2026, 2(1): 58-68 https://doi.org/10.1016/j.exm.2026.100021

Cui Zhou, Zhilin Tian, Liya Zheng, et al. Comparative study of water vapor corrosion resistance in directionally solidified RE₃Al₅O₁₂/Al₂O₃ eutectic ceramics at 1500°C: Effect of eutectic structure and rare earth elements[J]. Extreme Materials. 2026, 2(1): 58-68 https://doi.org/10.1016/j.exm.2026.100021

参考文献

列表( 原文顺序 | 文献年度倒序 | 文中引用次数倒序 ) 可视化分析

[1]	S. Krämer, J. Yang, C.G. Levi, C.A. Johnson, Thermochemical interaction of thermal barrier coatings with molten CaO-MgO-Al₂O₃-SiO₂ (CMAS) deposits, J. Am. Ceram. Soc. 89 (2006) 3167-3175. 本文引用 [1]

[2]	J. Li, Z.X. Luo, Y. Cui, G.H. Zhang, L.C. Sun, J.Y. Wang, CMAS corrosion resistance of Y₃AI₅O₁₂/Al₂O₃ ceramic coating deposited by atmospheric plasma spraying, J. Inorg. Mater. 39 (2024) 671-680. 本文引用 [1]

[3]	E.J. Opila, Oxidation and volatilization of silica formers in water vapor, J. Am. Ceram. Soc. 86 (2004) 1238-1248. 本文引用 [1]

[4]	J. Zhang, R.J. Liu, Y.J. Jian, F. Wan, Y.F. Wang, Degradation mechanism of SiCf/SiC composites after long-time water vapor and oxygen corrosion at 1300°C, Corros. Sci. 197 (2022) 110099. 本文引用 [1]

[5]	Y. Waku, N. Nakagawa, T. Wakamoto, H. Ohtsubo, K. Shimizu, Y. Kohtok, A ductile ceramic eutectic composite with high strength at 1873 K, Nature 389 (1997) 49-52. 本文引用 [1]

[6]	A. Henniche, J.H. Ouyang, Y.H. Ma, Z.G. Wang, Y.J. Wang, Z.G. Liu, Microstructure and mechanical properties of ceramics obtained from chemically co-precipitated Al₂O₃-GdAlO₃ nano-powders with eutectic composition, Ceram. Int. 43 (2017) 6996-7001. 本文引用 [1]

[7]	S. Yan, D.J. Wu, Y.F. Huang, N. Liu, Y.N. Zhang, F.Y. Niu, G.Y. Ma, C fiber toughening Al₂O₃-ZrO₂ eutectic via ultrasonic-assisted directed laser deposition, Mater. Lett. 235 (2019) 228-231. 本文引用 [1]

[8]	D.G. Liu, Y. Gao, J.L. Liu, F.Z. Liu, K. Li, H.J. Su, Y.G. Wang, L.N. An, Preparation of Al₂O₃-Y3Al₅O₁₂-ZrO₂ eutectic ceramic by flash sintering, Scr. Mater. 114 (2016) 108-111. 本文引用 [1]

[9]	S.Y. Zhai, J.C. Liu, Q. Liu, Changes in the microstructure and mechanical properties of Al₂O₃/YSZ directionally solidified eutectic ceramics during long-time heat treatment, J. Eur. Ceram. Soc. 41 (2021) 266-273. 本文引用 [1]

[10]	H.J. Su, Z.L. Shen, W.D. Ma, Y. Liu, D. Zhao, Y.N. Guo, Comprehensive microstructure regularization mechanism and microstructure-property stability at 1773K of directionally solidified Al₂O₃/GdAlO₃ eutectic ceramic composite, Compos. B Eng. 256 (2023) 110647. 本文引用 [1]

[11]	Y. Waku, N. Nakagawa, T. Wakamoto, H. Ohtsubo, K. Shimizu, Y. Kohtoku, High- temperature strength and thermal stability of a unidirectionally solidified Al₂O₃/ YAG eutectic composite, J. Mater. Sci. 33 (1998) 1217-1225. 本文引用 [1]

[12]	M.C. Mesa, S. Serrano-Zabaleta, P.B. Oliete, A. Larrea, Microstructural stability and orientation relationships of directionally solidified Al₂O₃-Er3Al₅O₁₂-ZrO₂ eutectic ceramics up to 1600°C, J. Eur. Ceram. Soc. 34 (2014) 2071-2080. 本文引用 [1]

[13]	H.J. Su, E.Y. Wang, Q. Ren, H.F. Liu, D. Zhao, G.Y. Fan, J. Zhang, L. Liu, H.Z. Fu, Microstructure tailoring and thermal stability of directionally solidified Al₂O₃/ GdAlO₃ binary eutectic ceramics by laser floating zone melting, Ceram. Int. 44 (2018) 7908-7916. 本文引用 [1]

[14]	M.C. Mesa, P.B. Oliete, V.M. Orera, J.Y. Pastor, A. Martín, J. Llorca, Microstructure and mechanical properties of Al₂O₃/Er3Al₅O₁₂ eutectic rods grown by the laser- heated floating zone method, J. Eur. Ceram. Soc. 31 (2011) 1241-1250. 本文引用 [1]

[15]	S.Q. Hao, H.J. Su, D. Zhao, X. Li, Z.L. Shen, Y. Liu, Y.N. Guo, Z. Zhang, M. Guo, Complex shaped Al₂O₃/YAG/ZrO₂ eutectic ceramics with excellent high temperature mechanical properties printed by vat photopolymerization, Addit. Manuf. 101 (2025) 104703. 本文引用 [1]

[16]	H.F. Sun, L.C. Sun, X.M. Ren, C. Zhou, J. Li, T.F. Du, J. Liu, J.Y. Wang, Outstanding molten calcium-magnesium-aluminosilicate (CMAS) corrosion resistance of directionally solidified Al₂O₃/Y3Al₅O₁₂ eutectic ceramic at 1500°C, Corros. Sci. 220 (2023) 111289. 本文引用 [1]

[17]	X. Tan, H.J. Su, Y. Liu, J.T. Yao, H.L. Gao, H. Jiang, M.H. Yu, X. Li, P.X. Yang, Z. Zhang, M. Guo, CMAS corrosion resistance and mechanism of directionally solidified Al₂O₃/YAG eutectic ceramics at high temperatures of 1300-1500 °C, Corros. Sci. 248 (2025) 112793. 本文引用 [1]

[18]	Y. Liu, H.J. Su, Z.L. Shen, D. Zhao, Y.N. Guo, X. Li, H. Jiang, D. Dong, C.B. Yang, High temperature calcium-magnesium-alumina-silicate (CMAS) corrosion behavior of directionally solidified Al₂O₃/YAG eutectic ceramic, J. Mater. Sci. Technol. 165 (2023) 66-74. 本文引用 [1]

[19]	N. Bahlawane, T. Watanabe, Y. Waku, A. Mitani, N. Nakagawa, Effect of moisture on the high-temperature stability of unidirectionally solidified Al₂O₃/YAG eutectic composites, J. Am. Ceram. Soc. 83 (2000) 3077-3081. 本文引用 [2]

[20]	A. Otsuka, Y. Waku, R. Tanaka, Corrosion of a unidirectionally solidified Al₂O₃/ YAG eutectic composite in a combustion environment, J. Eur. Ceram. Soc. 25 (2005) 1269-1274. 本文引用 [1]

[21]	C. Zhou, Z.P. Luo, T.F. Du, H.F. Sun, J.M. Wang, L.C. Sun, J.Y. Wang, Directionally solidified high-entropy (Y_0.2Gd_0.2Ho_0.2Er_0.2Yb_0.2)₃Al₅O₁₂/Al₂O₃ eutectic with outstanding crystallographic texture formation capability, Scr. Mater. 220 (2022) 114939. 本文引用 [2]

[22]	C. Zhou, L.C. Sun, T.F. Du, Z. Wu, J.M. Wang, J.Y. Wang, Excellent calcium-magnesium-aluminosilicate corrosion resistance of high-entropy garnet/alumina directionally solidified eutectic at 1500°C, J. Am. Ceram. Soc. 107 (2024) 1748-1759. 本文引用 [2]

[23]	Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, K.A. Dahmen, P.K. Liaw, Z.P. Lu, Microstructures and properties of high-entropy alloys, Prog. Mater. Sci. 61 (2014) 1-93. 本文引用 [2]

[24]	D.B. Miracle, O.N. Senkov, A critical review of high entropy alloys and related concepts, Acta Mater. 122 (2017) 448-511. 本文引用 [2]

[25]	J.W. Yeh, Recent progress in high-entropy alloys, Eur. J. Control 31 (2006) 633-648. 本文引用 [2]

[26]	Z.W. Xiong, K. Zhang, W.H. Liao, T.T. Liu, Y. Zhang, Z.G. Zhu, In-situ synthesis of high-entropy Al₂O₃/RE3Al₅O₁₂/ZrO₂ ceramic by laser powder bed fusion with exceptional properties, J. Adv. Ceram. 13 (2024) 2004-2020. 本文引用 [1]

[27]	B.L. Ye, T.Q. Wen, M.C. Nguyen, L.Y. Hao, C.Z. Wang, Y.H. Chu, First-principles study, fabrication and characterization of (Zr_0.25Nb_0.25Ti_0.25V_0.25)C high-entropy ceramics, Acta Mater. 170 (2019) 15-23. 本文引用 [1]

[28]	Z.F. Zhao, H. Chen, H.M. Xiang, F.Z. Dai, X.H. Wang, W. Xu, K. Sun, Z.J. Peng, Y.C. Zhou, High-entropy (Y_0.2Nd_0.2Sm_0.2Eu_0.2Er_0.2)AlO₃: a promising thermal/environmental barrier material for oxide/oxide composites, J. Mater. Sci. Technol. 47 (2020) 45-51. 本文引用 [1]

[29]	Z.F. Zhao, H.M. Xiang, H. Chen, F.Z. Dai, X.H. Wang, Z.J. Peng, Y.C. Zhou, High- entropy (Nd_0.2Sm_0.2Eu_0.2Y_0.2Yb_0.2)₄Al₂O₉ with good high temperature stability, low thermal conductivity, and anisotropic thermal expansivity, J. Adv. Ceram. 9 (2020) 595-605. 本文引用 [1]

[30]	Y. Dong, K. Ren, Y.H. Lu, Q.K. Wang, J. Liu, Y.G. Wang, High-entropy environmental barrier coating for the ceramic matrix composites, J. Eur. Ceram. Soc. 39 (2019) 2574-2579. 本文引用 [1]

[31]	X.T. Guo, Y.L. Zhang, T. Li, P.F. Zhang, K. Shuai, J. Li, X.H. Shi, High-entropy rare- earth disilicate (Lu_0.2Yb_0.2Er_0.2Tm₂Sc_0.2)₂Si₂O₇: A potential environmental barrier coating material, J. Eur. Ceram. Soc. 42 (2022) 3570-3578. 本文引用 [1]

[32]	H. Yoshida, A. Nakamura, T. Sakuma, N. Nakagawa, Y. Waku, Anisotropy in high- temperature deformation in unidirectionally solidified eutectic Al₂O₃-YAG single crystals, Scr. Mater. 45 (2001) 957-963. 本文引用 [1]

[33]	L.C. Sun, C. Zhou, T.F. Du, Z. Wu, Y.M. Lei, J.L. Li, H.J. Su, J.Y. Wang, Directionally solidified Al₂O₃/Er3Al₅O₁₂ and Al₂O₃/Yb3Al₅O₁₂ eutectic ceramics prepared by optical floating zone melting, J. Inorg. Mater. 36 (2021) 652-658. 本文引用 [1]

[34]	K.N. Lee, D.S. Fox, N.P. Bansal, Rare earth silicate environmental barrier coatings for SiC/SiC composites and Si₃N₄ ceramics, J. Eur. Ceram. Soc. 25 (2005) 1705-1715. 本文引用 [1]

[35]	H.F. Liu, H.J. Su, Z.L. Shen, H. Jiang, D. Zhao, Y. Liu, Y.N. Guo, X. Li, M. Guo, J. Zhang, L. Liu, H.Z. Fu, Formation mechanism and roles of oxygen vacancies in melt-grown Al₂O₃/GdAlO₃/ZrO₂ eutectic ceramic by laser 3D printing, J. Adv. Ceram. 11 (2022) 1751-1763. 本文引用 [1]

[36]	S. Ueno, D.D. Jayaseelan, T. Ohji, Development of oxide-based EBC for silicon nitride, Int. J. Appl. Ceram. Technol. 1 (2005) 362-373. 本文引用 [1]

[37]	M. Fritsch, H. Klemm, M. Herrmann, B. Schenk, Corrosion of selected ceramic materials in hot gas environment, J. Eur. Ceram. Soc. 26 (2006) 3557-3565. 本文引用 [1]

[38]	L. Mazerolles, N. Piquet, M.F. Trichet, L. Perrière, D. Boivin, M. Parlier, New microstructures in ceramic materials from the melt for high temperature applications, Aerosp. Sci. Technol. 12 (2008) 499-505. 本文引用 [1]

脚注

Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Thanks for supports from the National Key R&D Program of China (2024YFB3714504); National Natural Science Foundation of China (52130204, U21A2063); LiaoNing Revitalization Talents Program (XLYC2203090); International Partnership Program of the Chinese Academy of Sciences (172GJHZ2022094FN).