Deep-cooling thermal shock mechanisms of Ti3AlC2 ceramics in liquid nitrogen

Yijiang Liu; Yihan Liang; Chengwen Bin; Man Jiang; Qingguo Feng; Chunfeng Hu

doi:10.1016/j.exm.2026.100030

Extreme Materials ›› 0 2026 DOI: 10.1016/j.exm.2026.100030

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Deep-cooling thermal shock mechanisms of Ti₃AlC₂ ceramics in liquid nitrogen

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Abstract

This study employed liquid nitrogen to simulate a cryogenic environment. Ti₃AlC₂ samples were rapidly induction-heated in air and then cooled in liquid nitrogen. The results indicate that as the heating temperature increases, the residual flexural strength of the samples exhibits an overall trend of first rising to 590.8 MPa and decreasing later. It is noteworthy that due to the extremely low cooling temperature of liquid nitrogen, the oxide film on samples surface peels off upon exposure to liquid nitrogen at quenching temperatures below 720 ℃. Consequently, no significant oxides were detected during phase analysis. However, the oxide layer provides complete protection for the substrate, resulting in a slight recovery in flexural strength at 1100 ℃. Furthermore, the material exhibited a high Weibull modulus of 14.3 at 1250 ℃, demonstrating the exceptional thermal shock resistance and structural reliability of Ti₃AlC₂ under extreme cryogenic quenching conditions.

Key words

Ti₃AlC₂ / Thermal shock / Liquid nitrogen / Residual flexural strength / Weibull modulus

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Yijiang Liu , Yihan Liang , Chengwen Bin , et al . Deep-cooling thermal shock mechanisms of Ti₃AlC₂ ceramics in liquid nitrogen[J]. Extreme Materials. 2026 https://doi.org/10.1016/j.exm.2026.100030

References

List( Publishing order | Descend order by publishing year | Descend order by cited within ) Chart analysis

[1]	N.P. Padture. Advanced structural ceramics in aerospace propulsion. Nature Mater, 15 ( 2016), pp. 804-809, 10.1038/nmat4687. Cited in this article [2]

[2]	S. Dai, M. Li, X. Wu, Y. Wu, X. Li, Y. Hao, B. Luo. Combinatorial optimization of perovskite-based ferroelectric ceramics for energy storage applications. J. Adv. Ceram, 13 ( 2024), pp. 877-910, 10.26599/JAC.2024.9220904. Cited in this article [2]

[3]	M. Dahlqvist, M.W. Barsoum, J. Rosen. MAX phases-Past, present, and future. Mater. Today, 72 ( 2024), pp. 1-24, 10.1016/j.mattod.2023.11.010. Cited in this article [4]

[4]	H.B. Zhang, Y.C. Zhou, Y.W. Bao, M.S. Li. Abnormal thermal shock behavior of Ti₃SiC₂ and Ti₃AlC₂. J. Mater. Res., 21 ( 2006), pp. 2401-2407, 10.1557/jmr.2006.0289. Cited in this article [3]

[5]	W.K. Pang, I.M. Low, B.H. O'Connor, Z.M. Sun, K.E. Prince. Oxidation characteristics of Ti₃AlC₂ over the temperature range 500-900. Mater. Chem. Phys, 117 ( 2009), pp. 384-389, 10.1016/j.matchemphys.2009.06.016. Cited in this article [3]

[6]	Y.W. Bao, X.H. Wang, H.B. Zhang, Y.C. Zhou. Thermal shock behavior of Ti₃AlC₂ from between 200 ℃ and 1300 ℃. J. Eur. Ceram. Soc., 25 ( 2005), pp. 3367-3374, 10.1016/j.jeurceramsoc.2004.08.026. Cited in this article [3]

[7]	L. Yao, C.C. Zhu, J.X. Jiang, B.B. Zhou. Mechanical properties of Ti₃AlC₂ ceramics before and after heat treatment. Rare Met, 41 ( 2022), pp. 2777-2782, 10.1007/s12598-015-0609-z. Cited in this article [2]

[8]	E. Drouelle, V. Brunet, J. Cormier, P. Villechaise, P. Sallot, F. Naimi, F. Bernard, S. Dubois. Microstructure-oxidation resistance relationship in Ti3AlC2 MAX phase. J. Alloys Compd, 826 ( 2020), Article 154062, 10.1016/j.jallcom.2020.154062. Cited in this article [2]

[9]	Y. Liu, D. Zhu, S. Grasso, C. Hu. Microstructure and mechanical properties of gel casted Ti₃AlC₂. Ceram. Inter, 44 ( 2018), pp. 23254-23258, 10.1016/j.ceramint.2018.08.269. Cited in this article [2]

[10]	G. Han, J.-R. Lee, Y. Noh, T.-S. Jun. The role of cryogenic quenching on the mechanical properties of FSWed 6061-T₆ aluminum alloy. Mater. Sci. Eng.: A, 840 ( 2022), Article 142896, 10.1016/j.msea.2022.142896. Cited in this article [2]

[11]	B. Hu, Y. Bao, X. Su, D. Wan, Q. Feng, S. Grasso, C. Hu. Comparative investigation of ultrafast thermal shock of Ti₃AlC₂ ceramic in water and air. Int. J. Appl. Ceram. Technol, 18 ( 2021), pp. 1863-1871, 10.1111/ijac.13811. Cited in this article [7]

[12]	L. Cao, Q. Zhang, L. Du, S. Fu, D. Wan, Y. Bao, Q. Feng, C. Hu. Synthesis and characterization of high entropy (TiVNbTaM)₂AlC (M = Zr, Hf) ceramics. J. Adv. Ceram, 13 ( 2024), pp. 237-246, 10.26599/JAC.2024.9220847. Cited in this article [2]

[13]	H. Reinheimer, M.M. Maye. Preparing superconducting YBCO colloids via a top-down processing route for applications in soft composites. ACS Omega, 10 ( 2025), pp. 56401-56410, 10.1021/acsomega.5c08369. Cited in this article [2]

[14]	M. Gan, T. Lu, W. Yu, J. Feng, X. Chong. Capturing and visualizing the phase transition mediated thermal stress of thermal barrier coating materials via a cross-scale integrated computational approach. J. Adv. Ceram, 13 ( 2024), pp. 413-428, 10.26599/JAC.2024.9220864. Cited in this article [1]

[15]	H. Zhang, B. Hu, B. Dai, L. Chu, Q. Feng, C. Hu. Excellent ablation resistance of Ti₃AlC₂ ceramics up to 1900 ℃ in nitrogen plasma flame. J. Eur. Ceram. Soc., 44 ( 2024), pp. 1436-1444, 10.1016/j.jeurceramsoc.2023.10.064. Cited in this article [2]

[16]	X. Su, Y. Bao, D. Wan, H. Zhang, L. Xu, S. Grasso, C. Hu. Thermal shock resistance of Ti₃SiC₂ ceramic under extremely rapid thermal cycling. J. Alloys Compd, 866 ( 2021), Article 158985, 10.1016/j.jallcom.2021.158985. Cited in this article [1]

[17]	M.W. Barsoum, M. Radovic. Elastic and mechanical properties of the MAX phases. Annu. Rev. Mater. Res., 41 ( 2011), pp. 195-227, 10.1146/annurev-matsci-062910-100448. Cited in this article [1]

[18]	M.W. Barsoum. The M_N+1AX_N phases: A new class of solids. Prog. Solid State Chem, 28 ( 2000), pp. 201-281, 10.1016/S0079-6786(00)00006-6. Cited in this article [1]

[19]	Z.M. Sun. Progress in research and development on MAX phases: A family of layered ternary compounds. Int. Mater. Rev., 56 ( 2011), pp. 143-166, 10.1179/1743280410Y.0000000001. Cited in this article [1]

[20]	H. Li, Y. Tian, D. Wan, Y. Bao, Y. Zhou. Effect of thermal stability of M_n+1AX_n phases on microstructure and mechanical properties of M_n+1AX_n/ZA27 composites. Int. J. Appl. Ceram. Technol, 18 ( 2021), 10.1111/ijac.13741. Cited in this article [1]

[21]	N.V. Tzenov, M.W. Barsoum. Synthesis and characterization of Ti₃AlC₂. J. Am. Ceram. Soc., 83 ( 2000), pp. 825-832, 10.1111/j.1151-2916.2000.tb01281.x. Cited in this article [1]

[22]

Goc

, W.

Prendota

, L.

Chlubny

, T.

Strączek

, W.

Tokarz

, P.B.

Chachlowska

, K.W.

Chabior

, M.M.

Bućko

, J.

Przewoźnik

, J.

Lis

. Structure, morphology and electrical transport properties of the Ti₃AlC₂ materials. Ceram. Inter, 44 ( 2018), pp. 18322-18328, 10.1016/j.ceramint.2018.07.045.

Cited in this article [2]

[23]	X. Li, Y. Qian, L. Zheng, J. Xu, M. Li. Determination of the critical content of Al for selective oxidation of Ti₃AlC₂ at 1100 ℃. J. Eur. Ceram. Soc., 36 ( 2016), pp. 3311-3318, 10.1016/j.jeurceramsoc.2016.05.008. Cited in this article [3]

[24]	Y. Yu, S. Fu, D. Wan, Y. Bao, L. Chu, Q. Feng, C. Hu. Hot forging Nb₄AlC₃ ceramics with enhanced properties. J. Adv. Ceram, 12 ( 2023), pp. 2032-2040, 10.26599/JAC.2023.9220805. Cited in this article [3]

[25]	T. Lapauw, A.K. Swarnakar, B. Tunca, K. Lambrinou, J. Vleugels. Nanolaminated ternary carbide (MAX phase) materials for high temperature applications. Int. J. Refract. Met. Hard Mater, 72 ( 2018), pp. 51-55, 10.1016/j.ijrmhm.2017.11.038. Cited in this article [3]

[26]

, Y.

Sakka

, H.

Tanaka

, T.

Nishimura

, S.

Grasso

. Low temperature thermal expansion, high temperature electrical conductivity, and mechanical properties of Nb₄AlC₃ ceramic synthesized by spark plasma sintering. J. Alloys Compd, 487 ( 2009), pp. 675-681, 10.1016/j.jallcom.2009.08.036.

Cited in this article [3]

[27]	X. Duan, Z. Fang, T. Yang, C. Guo, Z. Han, D. Sarker, X. Hou, E. Wang. Maximizing the mechanical performance of Ti₃AlC₂-based MAX phases with aid of machine learning. J. Adv. Ceram, 11 ( 2022), pp. 1307-1318, 10.1007/s40145-022-0612-4. Cited in this article [3]

[28]	Y. Jiang, R. Xu, R. Jiang, F. Yang, H. Liu, X. Sun. High-temperature mechanical properties and thermal shock resistance of an alumina-fiber-reinforced alumina ceramic matrix composite. Ceram. Inter, 51 ( 2025), pp. 5459-5469, 10.1016/j.ceramint.2024.11.502. Cited in this article [1]

[29]	W. Zhang, S. Li, S. Fan, X. Zhang, X. Fan, G. Bei. Ti3AlC_2-yN_y carbonitride MAX phase solid solutions with tunable mechanical, thermal and electrical properties. J. Adv. Ceram ( 2024), 10.26599/JAC.2024.9220951. Cited in this article [2]

[30]	X.L. Ma, Y.L. Zhu, X.H. Wang, Y.C. Zhou. Microstructural characterization of bulk Ti₃AlC₂ ceramics. Philos. Mag., 84 ( 2004), pp. 2969-2977, 10.1080/14786430410001716197. Cited in this article [2]

[31]

Zhou

, K.

, J.

Zhu

, R.

. situ synthesis, mechanical and cyclic oxidation properties of Ti₃AlC₂/Al₂O₃ composites. Adv. Appl. Ceram ( 2018). https://journals.sagepub.com/doi/abs/10.1080/17436753.2018.1434953△https://journals.sagepub.com/doi/abs/10.1080/17436753.2018.1434953△.

Cited in this article [1]

[32]	T. Jiang. Fabrication technology, research and development status, development trend of the ternary laminated structure MAX phase ceramics materials. Adv. Ceram, 44 ( 2023), pp. 1-23, 10.16253/j.cnki.37-1226/tq.2023.01.001. Cited in this article [2]

[33]	H. Kou, W. Li, X. Zhang, J. Shao, X. Zhang, P. Geng, Y. Deng, J. Ma. Effects of mechanical shock on thermal shock behavior of ceramics in quenching experiments. Ceram. Inter, 43 ( 2017), pp. 1584-1587, 10.1016/j.ceramint.2016.10.021. Cited in this article [1]

[34]	B. Li, Y. Yan, X. Jin, Y. Geng, S. Wang, M. Cao, X. He, N. Li, Y. Zhuang. Microstructure and mechanical and thermal shock properties of hierarchically porous ceramics. Ceram. Inter, 47 ( 2021), pp. 24887-24894, 10.1016/j.ceramint.2021.05.215. Cited in this article [1]

[35]	M. Han, J. Huang, S. Chen. Behavior and mechanism of the stress buffer effect of the inside ceramic layer to the top ceramic layer in a double-ceramic-layer thermal barrier coating. Ceram. Inter, 40 ( 2014), pp. 2901-2914, 10.1016/j.ceramint.2013.10.021. Cited in this article [1]

[36]	S. Qian, F. Liu, M. Ma, G. Chen, Z. Liu, Y. Li. Mechanical strength enhancement of low temperature co-fired multilayer ceramic substrates by introducing residual stress. Ceram. Inter, 45 ( 2019), pp. 10982-10990, 10.1016/j.ceramint.2019.02.181. Cited in this article [1]

[37]	S. Guo, Q. Kang, J. Liu, X. Qu. Fabrication of Ti₃AlC₂ ceramic material by mechanical alloying. Rare Met, 29 ( 2010), pp. 376-379, 10.1007/s12598-010-0133-0. Cited in this article [1]

[38]	L. Chen, S. Wang, C. Li, H.X. Zhang, G.J. Yang. Durable RSZ/YSZ coatings with 1600 ℃ thermal shock resistance for rocket engine thrust chamber applications. Ceram. Inter, 51 ( 2025), pp. 54903-54913, 10.1016/j.ceramint.2025.09.216. Cited in this article [2]

[39]

Nevarez-Rascon

, A.

Aguilar-Elguezabal

, E.

Orrantia

, M.H.

Bocanegra-Bernal

. Compressive strength, hardness and fracture toughness of Al₂O₃ whiskers reinforced ZTA and ATZ nanocomposites: Weibull analysis. Int. J. Refract. Met. Hard Mater, 29 ( 2011), pp. 333-340, 10.1016/j.ijrmhm.2010.12.008.

Cited in this article [1]

[40]	Y. Liu, W. Ding, Z. Teng, Y. Bao, M. Jiang, Q. Feng, C. Hu. Ultra-fast thermal shock mechanisms of Ti₃AlC₂ ceramics in a low oxygen environment. Int. J. Applied Ceram. Tech, 22 ( 2025), Article e70045, 10.1111/ijac.70045. Cited in this article [2]

[41]	W. Ding, H. Chen, Y. Bao, L. Chu, Q. Feng, C. Hu. Ultra-fast thermal shock behavior of Cr₂AlC ceramics up to 1300 ℃. Ceram. Inter, 50 ( 2024), pp. 12074-12080, 10.1016/j.ceramint.2024.01.110. Cited in this article [1]