Extreme Materials

Advances in ultra-high-temperature ceramic coatings with enhanced oxidation resistance for carbon-based composites

Xuanru Ren, Peipei Wang, Yuexing Chen, Wei Xie, Xiang Ji, Zhichao Shang, Chengshan Ji, Jun Zhao, Huiqun Liu, Guozheng Lv, Peizhong Feng

Extreme Materials, 2025, 1(3): 9-43. DOI: 10.1016/j.exm.2025.07.003

Coating materials	Fabrication methods	Temperature ( ^∘C )	Time (h)	Mass loss (wt%)	Refs.
ZrB₂-ZrC-SiC	LC	1500	0.8	0.51 g/cm²	[21]
SiC	PEM + CVI	1500	100	7.75 g/cm²	[22]
B₄C-HfB₂-SiC	ISR	1200	104	5.45 %	[23]
ZrB₂-SiC	LPS	1500	200	0.14 %	[25]
ZrB₂	SCC	1500	342	1.03 %	[28]
ZrB₂-CrSi₂-SiC-Si/SiC	IMP	1500		1.74 %	[29]
HfB₂-SiC/SiC	ISR	1500	753	0.487 %	[30]
HfB₂-SiC-MoSi₂-Si/SiC-	-	1650	618	57.9 %	[32]
Si
${\mathrm{Z}\mathrm{r}\mathrm{B}}_{2}-\mathrm{S}\mathrm{i}\mathrm{C}-\mathrm{S}\mathrm{i}/{\mathrm{Y}\mathrm{b}}_{2}{\mathrm{S}\mathrm{i}\mathrm{O}}_{5}/{\mathrm{L}\mathrm{a}\mathrm{M}\mathrm{g}\mathrm{A}\mathrm{l}}_{11}{\mathrm{O}}_{19}$	2000			0.3 %	[33]
$\mathrm{S}\mathrm{i}\mathrm{C}/\mathrm{S}\mathrm{i}-{\mathrm{Z}\mathrm{r}\mathrm{S}\mathrm{i}}_{2}-{\mathrm{Z}\mathrm{r}\mathrm{B}}_{2}-{\mathrm{H}\mathrm{f}\mathrm{B}}_{2}/\mathrm{S}\mathrm{i}\mathrm{C}$	PIP	1300	120	1.25 %	[38]
SiCw	CVD	1500	72	0.5 %	[41]
SiCw-/ZrB₂-ZrSiO₄		1500	20	120.17 g/cm²	[43]
SiC_w-SiC-MoSi₂-ZrB₂	CVD	1500	124	1.1mg/cm²	[44]
ZrB₂-SiC_w-BSG/ZrB₂	-	1500	1.5	0.44 %	[45]
-MoSi₂-SiC_w-BSG
SiC_w-HfB₂-SiC-Si/SiC	-	1500	468	0.88 %	[46]

Table 1 High temperature oxidation resistance of single layer coating, double layer coating, gradient coating and nanomaterial coating.

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